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Heterofullerenes are classes of fullerenes, at least one carbon atom is replaced by another element.[1][2] Based on spectroscopy, substitutions have been reported with boron (borafullerenes),[3][4] nitrogen (azafullerenes),[5][6] oxygen,[7] arsenic, germanium,[8] phosphorus,[9] silicon,[10][11] iron, copper, nickel, rhodium[11][12] and iridium.[11] Reports on isolated heterofullerenes are limited to those based on nitrogen [13][14][15][16][17] and oxygen.[18]

References

  1. ^ Vostrowsky, O.; Hirsch, A. (2006). "Heterofullerenes". Chemical Reviews. 106 (12): 5191–5207. doi:10.1021/cr050561e. PMID 17165685.
  2. ^ Hummelen, Jan C.; Bellavia-Lund, Cheryl; Wudl, Fred (1999). "Heterofullerenes. Fullerenes and Related Structures". Topics in Current Chemistry. 199: 93–134. doi:10.1007/3-540-68117-5_3.
  3. ^ Chai, Y.; Guo, T.; Jin, C.; Haufler, R. E.; Chibante, L. P. F.; Fure, J.; Wang, L.; Alford, J. M.; Smalley, R. E. (1991). "Fullerenes with metals inside". The Journal of Physical Chemistry. 95 (20): 7564. doi:10.1021/j100173a002.
  4. ^ Muhr, H. -J.; Nesper, R.; Schnyder, B.; Kötz, R. (1996). "The boron heterofullerenes C59B and C69B: Generation, extraction, mass spectrometric and XPS characterization". Chemical Physics Letters. 249 (5–6): 399. Bibcode:1996CPL...249..399M. doi:10.1016/0009-2614(95)01451-9.
  5. ^ Averdung, J.; Luftmann, H.; Schlachter, I.; Mattay, J. (1995). "Aza-dihydro[60]fullerene in the gas phase. A mass-spectrometric and quantumchemical study". Tetrahedron. 51 (25): 6977. doi:10.1016/0040-4020(95)00361-B.
  6. ^ Lamparth, I.; Nuber, B.; Schick, G.; Skiebe, A.; Grösser, T.; Hirsch, A. (1995). "C59N+ and C69N+: Isoelectronic Heteroanalogues of C60 and C70". Angewandte Chemie International Edition in English. 34 (20): 2257. doi:10.1002/anie.199522571.
  7. ^ Christian, J. F.; Wan, Z.; Anderson, S. L. (1992). "O++C60•C60O+ production and decomposition, charge transfer, and formation of C59O+. Dopeyball or [CO@C58]+". Chemical Physics Letters. 199 (3–4): 373. Bibcode:1992CPL...199..373C. doi:10.1016/0009-2614(92)80134-W.
  8. ^ Ohtsuki, T.; Ohno, K.; Shiga, K.; Kawazoe, Y.; Maruyama, Y.; Masumoto, K. (1999). "Formation of As- and Ge-doped heterofullerenes". Physical Review B. 60 (3): 1531. Bibcode:1999PhRvB..60.1531O. doi:10.1103/PhysRevB.60.1531.
  9. ^ Möschel, C.; Jansen, M. (1999). "Darstellung stabiler Phosphor-Heterofullerene im Hochfrequenzofen". Z. Anorg. Allg. Chem. 625 (2): 175–177. doi:10.1002/(SICI)1521-3749(199902)625:2<175::AID-ZAAC175>3.0.CO;2-2.
  10. ^ Pellarin, M.; Ray, C.; Lermé, J.; Vialle, J. L.; Broyer, M.; Blase, X.; Kéghélian, P.; Mélinon, P.; Perez, A. (1999). "Photolysis experiments on SiC mixed clusters: From silicon carbide clusters to silicon-doped fullerenes". The Journal of Chemical Physics. 110 (14): 6927–6938. Bibcode:1999JChPh.110.6927P. doi:10.1063/1.478598.
  11. ^ a b c Billas, I.M.L.; Branz, W.; Malinowski, N.; Tast, F.; Heinebrodt, M.; Martin, T.P.; Massobrio, C.; Boero, M.; Parrinello, M. (1999). "Experimental and computational studies of heterofullerenes". Nanostructured Materials. 12 (5–8): 1071–1076. doi:10.1016/S0965-9773(99)00301-3.
  12. ^ Branz, W.; Billas, I. M. L.; Malinowski, N.; Tast, F.; Heinebrodt, M.; Martin, T. P. (1998). "Cage substitution in metal–fullerene clusters". The Journal of Chemical Physics. 109 (9): 3425. Bibcode:1998JChPh.109.3425B. doi:10.1063/1.477410.
  13. ^ Harris, D.J. (1993) "Discovery of Nitroballs: Research in Fullerene Chemistry" http://www.usc.edu/CSSF/History/1993/CatWin_S05.html Archived 2015-11-29 at the Wayback Machine
  14. ^ Hummelen, J. C.; Knight, B.; Pavlovich, J.; Gonzalez, R.; Wudl, F. (1995). "Isolation of the Heterofullerene C59N as Its Dimer (C59N)2" (PDF). Science. 269 (5230): 1554–1556. Bibcode:1995Sci...269.1554H. doi:10.1126/science.269.5230.1554. hdl:11370/ffe5ba8c-5336-4aed-9c78-0a26f31d459d. PMID 17789446. S2CID 31270587.
  15. ^ Keshavarz-K, M.; González, R.; Hicks, R. G.; Srdanov, G.; Srdanov, V. I.; Collins, T. G.; Hummelen, J. C.; Bellavia-Lund, C.; Pavlovich, J.; Wudl, F.; Holczer, K. (1996). "Synthesis of hydroazafullerene C59HN, the parent hydroheterofullerene". Nature. 383 (6596): 147. Bibcode:1996Natur.383..147K. doi:10.1038/383147a0. S2CID 4315682.
  16. ^ Nuber, B.; Hirsch, A. (1996). "A new route to nitrogen heterofullerenes and the first synthesis of (C69N)2". Chemical Communications (12): 1421. doi:10.1039/CC9960001421.
  17. ^ Zhang, G.; Huang, S.; Xiao, Z.; Chen, Q.; Gan, L.; Wang, Z. (2008). "Preparation of Azafullerene Derivatives from Fullerene-Mixed Peroxides and Single Crystal X-ray Structures of Azafulleroid and Azafullerene". Journal of the American Chemical Society. 130 (38): 12614–12615. doi:10.1021/ja805072h. PMID 18759401.
  18. ^ Xin, N.; Huang, H.; Zhang, J.; Dai, Z.; Gan, L. (2012). "Fullerene Doping: Preparation of Azafullerene C59NH and Oxafulleroids C59O3 and C60O4". Angewandte Chemie International Edition. 51 (25): 6163–6166. doi:10.1002/anie.201202777. PMID 22573566.


source: http://en.wikipedia.org/wiki/Heterofullerene