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Potassium ethoxide

Names
Preferred IUPAC name Potassium ethoxide
Other names Potassium ethylate
Identifiers
CAS Number	917-58-8
3D model (JSmol)	Interactive image
ChemSpider	63375
ECHA InfoCard	100.011.845
EC Number	213-029-0
PubChem CID	23670592
CompTox Dashboard (EPA)	DTXSID10890530
InChI InChI=1S/C2H5O.K/c1-2-3;/h2H2,1H3;/q-1;+1 Key: RPDAUEIUDPHABB-UHFFFAOYSA-N InChI=1/C2H5O.K/c1-2-3;/h2H2,1H3;/q-1;+1 Key: RPDAUEIUDPHABB-UHFFFAOYAN
SMILES CC[O-].[K+]
Properties
Chemical formula	C2H5KO
Molar mass	84.159 g·mol−1
Appearance	Yellow or Off-White Powder[1]
Density	0.894 g/mL [2]
Melting point	250 °C (482 °F; 523 K)
Solubility in water	Reacts
Hazards
GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H251, H314
Precautionary statements	P235+P410, P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, P407, P413, P420, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Potassium ethoxide, also known as potassium ethanolate, is an off-white or yellow powder with the chemical formula of C₂H₅KO. Potassium ethoxide contains an ethoxide ion, the conjugate base of ethanol, which makes these compounds strongly basic. It hydrolyzes to yield ethanol and potassium hydroxide.

Uses

Potassium ethoxide is used as a strong base, similar to sodium and potassium methoxides, and potassium tert-butoxide. Catalytic amounts of potassium ethoxide in ethanol can be used to perform transesterification reactions that yield ethyl esters. Sodium or potassium ethoxide is also a suitable base for the malonic ester synthesis where diethyl malonate is used, since any transesterification reaction does not result in ester scrambling.

Safety

Potassium ethoxide is stable, but also both flammable and corrosive. The compound reacts vigorously with water. If the compound comes into contact with damp air, it may lead to the heating and ignition of the solid powder. It must be kept separated from air, moisture, water, acids, oxidizing agents, and reducing agents.^[3] It can also cause severe skin burns.^[4]

References