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Maria Carolina or Marie Caroline may refer to:

Royalty

Maria Karolina Sobieska (1697–1740), Princess of Turenne and Duchess of Bouillon
Archduchess Maria Carolina of Austria (born 1740) (1740–1741), daughter of Empress Maria Theresa and Emperor Francis I
Archduchess Maria Carolina of Austria (stillborn 1748), daughter of Empress Maria Theresa and Emperor Francis I
Maria Carolina of Austria (1752–1814), Queen of Naples and Sicily from 1768 to 1814, daughter of Empress Maria Theresa and Emperor Francis I
Princess Maria Carolina of Savoy (1764–1782), Electoral Princess of Saxony
Maria Caroline Gibert de Lametz (1793–1879), Princess of Monaco
Marie-Caroline of Bourbon-Two Sicilies, Duchess of Berry (1798–1870), Duchess of Berry
Archduchess Marie Caroline of Austria (1801–1832), Crown Princess of Saxony
Princess Maria Carolina of Bourbon-Two Sicilies (1820–1861), Countess of Montemolin
Princess Maria Carolina of Bourbon-Two Sicilies (1822–1869), Duchess of Aumale
Archduchess Maria Karoline of Austria (1825–1915), granddaughter of Emperor Leopold II
Princess Maria Carolina of Bourbon-Two Sicilies (1856–1941), Countess Maria Carolina Zamoyska
Princess Maria Karoline of Saxe-Coburg and Gotha (1899–1941), daughter of Prince August Leopold of Saxe-Coburg and Gotha
Princess Marie-Caroline of Liechtenstein (born 1996), daughter of Alois, Hereditary Prince of Liechtenstein
Princess Maria Carolina of Bourbon (born 2003), daughter of Prince Carlo, Duke of Castro

Marie Caroline Bjelke-Petersen (1874–1969), Danish-Australian novelist
Maria Veleda (Maria Carolina Frederico Crispin, 1871–1955), Portuguese educator, journalist and activist
Maria Carolina Gomes Santiago (born 1985), Brazilian Paralympic swimmer
Carolina Herrera (born 1939), born María Carolina Josefina Pacanins y Niño, Venezuelan fashion designer
Marie-Caroline Le Pen (born 1960), daughter of Jean-Marie Le Pen
Carolina Luján (María Carolina Luján, born 1985), Argentine chess player
Marie Caroline Miolan-Carvalho (1827–1895), French soprano
María Carolina Santa Cruz (born 1978), Argentine swimmer
Maria Carolina Wolf (1742–1820), German pianist, singer and composer